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    • BORANE-METHYL SULFIDE COMPLEX, 2.0M SOLU

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    Documents SDS COO/COA Specification Sheet
    192120
    Sigma-Aldrich

    BORANE-METHYL SULFIDE COMPLEX, 2.0M SOLU

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    Linear Formula:

    (CH3)2S · BH3

    Empform:

    C2H9BS

    Synonyms English:

    BMS

    Nacres: NA.22
    Mdl No: MFCD00013189
    Fw: 75.97
    Pubchem Substance Id: 24851530
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    Documents SDS COO/COA Specification Sheet

    Properties

    Properties
    concentration 2.0 
    concentricity M in THF
    density of sugar measuring range 0.855 
    depth g/mL 
    depth × h × w at 25 
    depth × overall h ?C
    frame size liquid
    inlet and outlet diam. 1S/C2H6S.BH3/c1-3-2
    inlet and outlet nptm × nptm /h1-2H3
    inlet and outlet size 1H3
    inlet cga RMHDLBZYPISZOI-UHFFFAOYSA-N
    Import License Discarded/Inactive
    Check Obsolete No
    Temperature Control 2 - 8
    Shipping Mode DAS
    Business Unit Chemistry

    Description

    Application

    Borane dimethyl sulfide complex (BMS) solution may be used in the following studies:
    • One-pot conversion of alkynes into 1,2-diols.
    • Preparation of iminopentitols.
    • Reduction of representative organic functional groups, such as esters, nitriles and amides.
    • Used along with a dendrimeric supported L-pyrrolidinol in the asymmetric reduction of indanones and tetralones.
    • Asymmetric reduction of ferrocenyl-1,3-diketones to chiral 1,3-diols.
    • Highly enantioselective reduction of ketones catalyzed by C3-symmetric tripodal hydroxyamides.

    General description

    Borane dimethyl sulfide complex (BMS) acts as a highly efficient and selective reducing agent in the presence of catalytic sodium tetrahydroborate for α

    Immunogen

    -hydroxy esters. Asymmetric borane reduction of a variety of prochiral ketones with BMS using spiroborate esters as catalyst has been reported.

    SAFETY INFORMATION

    GHS02,GHS05,GHS07,GHS08

    Signal Word

    Danger

    H225 - H260 - H302 + H312 - H318 - H335 - H336 - H351 - H360FD

    P210 - P231 + P232 - P280 - P303 + P361 + P353 - P305 + P351 + P338 - P308 + P313

    RIDADRRIDADR

    WGK Germany

    WGK 1

    Flash Point (F)

    1.4 °F - closed cup

    Flash Point (C)

    -17 °C - closed cup

    Target Organs

    Risk Statement

    Supplemental Hazard Statements

    TECHNICAL SERVICE

    Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.