200107
Sigma-Aldrich

SELENIUM DIOXIDE, >=99.9% TRACE METALS B

Linear Formula:

SeO2

Empform:

O2Se

Synonyms English:

NSC 56753

Nacres: NA.22
Mdl No: MFCD00003562
Fw: 110.96
Pubchem Substance Id: 24851959
CAS Number: 7446-08-4
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Properties

Properties
assay
assay range 99.9% trace metals basis
Description SELENIUM DIOXIDE, >=99.9% TRACE METALS B
format solid
inchi key 1S/O2Se/c1-3-2
indiff. to chromic acid JPJALAQPGMAKDF-UHFFFAOYSA-N
Import License Temp. Regu
Check Obsolete No
Temperature Control 1554
Shipping Mode DAS
Business Unit Chemistry

Description

Application

Selenium dioxide (SeO2) can be used as:
  • An oxidizing agent to introduce carbonyl functional groups at activated carbon.
  • A catalyst in the allylic hydroxylation reactions.
  • An oxidant in the synthesis of amides by oxidative amidation of aldehydes with amines.
  • A catalyst to synthesize di and trioxidized bicyclic cyclopentenones by reacting with Pauson-Khand reaction (PKR) products.
  • A catalyst along with iodine (I2) to prepare mono and bis-sulfenylindoles by treating indoles with diaryl disulfides via C-H sulfenylation.
  • A catalyst to synthesize alkyl and aryl nitriles from the corresponding aldehydes via the formation of aldoxime.
  • A selenium precursor to synthesize FeSe nanostructures via electrochemical deposition method.

It can also be used as a versatile reagent for allylic oxidation and oxidative-elimination reactions.

SAFETY INFORMATION

GHS06,GHS08,GHS09

Signal Word

Danger

H301 + H331 - H373 - H410

P273 - P301 + P310 + P330 - P304 + P340 + P311 - P314

RIDADRRIDADR

WGK Germany

WGK 2

Flash Point (F)

Not applicable

Flash Point (C)

Not applicable

Target Organs

Risk Statement

Supplemental Hazard Statements

DOCUMENTATION

Certificate of Analysis View Sample COA
Certificate of Origin

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